Resonance Stabilized Bisdiselenazolyls as Neutral Radical Conductors
Journal of the American Chemical Society2006Vol. 128(47), pp. 15080–15081
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Jaclyn L. Brusso, K. Cvrkalj, Alicea A. Leitch, Richard T. Oakley, Robert W. Reed, Craig M. Robertson
Abstract
An efficient and versatile synthetic route to resonance stabilized bisselenathiazolyl and bisdiselenazolyl radicals 3 and 4 is described. Structural analysis of 3 and 4 confirm that lattice and pi-delocalization energies are sufficient to offset solid-state dimerization of the radicals and that the two selenium-containing radicals are isostructural with the all-sulfur based system 1. Variable temperature conductivity measurements indicate that sequential replacement of sulfur by selenium leads to a progressive increase in conductivity and reduction in thermal activation energy.
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