The Total Synthesis of (±)-11-O-Debenzoyltashironin
Journal of the American Chemical Society2006Vol. 128(51), pp. 16440–16441
Citations Over TimeTop 10% of 2006 papers
Abstract
The total synthesis of the putative non-peptidyl neurotrophic factor 11-O-debenzoyltashironin has been accomplished. The key transformation involves a biomimetic oxidative dearomatization/transannular Diels-Alder sequence that closes the tetracyclic carbon skeleton present in the natural product.
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