An Activated Equivalent of Lactide toward Organocatalytic Ring-Opening Polymerization
Journal of the American Chemical Society2006Vol. 128(51), pp. 16442–16443
Citations Over TimeTop 12% of 2006 papers
Olivier Thillaye Du Boullay, Emmanuel Marchal, Blanca Martín-Vaca, Fernando P. Cossío, Didier Bourissou
Abstract
The alpha-lactone equivalent lacOCA exhibits remarkable reactivity compared with lactide in nucleophile-catalyzed ROP. PLAs of controlled molecular weights and narrow polydispersities are typically obtained under mild conditions using DMAP and various protic initiators.
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