Highly Enantiomeric Supramolecular [4 + 4] Photocyclodimerization of 2-Anthracenecarboxylate Mediated by Human Serum Albumin
Journal of the American Chemical Society2007Vol. 129(12), pp. 3478–3479
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Abstract
Photoirradiation at λ > 320 nm of 2-anthracenecarboxylate bound to human serum albumin in an aqueous buffer solution at 5 °C gave syn head-to-tail cyclodimer 2 in 82% ee and anti head-to-head cyclodimer 3 in 90% ee.
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