anti-[2.2](1,4)Phthalocyaninophane: Spectroscopic Evidence for Transannular Interaction in the Excited States
Journal of the American Chemical Society2007Vol. 129(15), pp. 4516–4517
Citations Over TimeTop 11% of 2007 papers
Yoshiaki Asano, Atsuya Muranaka, Akira Fukasawa, Terutaka Hatano, Masanobu Uchiyama, Nagao Kobayashi
Abstract
The design and synthesis of a novel type of bisphthalocyanines, anti-[2.2](1,4)phthalocyaninophanes, were reported. The phthalocyanine dimer exhibited significantly split and red-shifted absorption in the near-IR region and maintained the fluorescence properties of phthalocyanines. The origin of the electronic communication between the two phthalocyanines was rationalized on the basis of the MO model analysis.
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