Gold(I)-Catalyzed Enantioselective Intramolecular Hydroamination of Allenes
Journal of the American Chemical Society2007Vol. 129(9), pp. 2452–2453
Citations Over TimeTop 1% of 2007 papers
Abstract
The asymmetric intramolecular hydroamination of allenes catalyzed by phosphinegold(I)−bis-p-nitrobenzoate complexes is described. This reaction is applicable to the enantioselective formation of vinyl pyrrolidines and piperidines in 70−99% ee.
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