A Palladium-Catalyzed Cyclization−Oxidation Sequence: Synthesis of Bicyclo[3.1.0]hexanes and Evidence for SN2 C−O Bond Formation
Journal of the American Chemical Society2007Vol. 129(16), pp. 4906–4907
Citations Over TimeTop 10% of 2007 papers
Abstract
A novel palladium-catalyzed cyclization−oxidation sequence yielding bicyclo[3.1.0]hexanes was developed. A mechanism involving a Pd(II)/Pd(IV) cycle was proposed. An SN2 C−O bond formation from an alkyl−palladium(IV) intermediate was also suggested.
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