“Open Rather than Closed” Malonate Methano-Fullerene Derivatives. The Formation of Methanofulleroid Adducts of Y3N@C80
Journal of the American Chemical Society2007Vol. 129(34), pp. 10423–10430
Citations Over TimeTop 10% of 2007 papers
Olena Lukoyanova, Claudia M. Cardona, José A. Rivera, Leyda Z. Lugo‐Morales, Christopher J. Chancellor, Marilyn M. Olmstead, Antonio Rodríguez‐Fortea, Josep M. Poblet, Alan L. Balch, Luís Echegoyen
Abstract
Cycloaddition of bromomalonates to Y3N@C80 unexpectedly gave rise to fulleroid derivatives with unusually high stability. Complete characterization of these derivatives is described including X-ray crystallography, 1H NMR, 13C NMR, HMQC, UV-visible, HPLC, MALDI-MS, and electrochemistry. Density functional theory calculations are also presented, which provide a rationale for the formation of the fulleroid and reveal the underlying thermodynamic basis for their stability.
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