Bottom up Synthesis That Does Not Start at the Bottom: Quadruple Covalent Cross-Linking of Nanoscale Faceted Polyhedra
Journal of the American Chemical Society2007Vol. 129(33), pp. 10076–10077
Citations Over TimeTop 1% of 2007 papers
Abstract
A novel 3D metal−organic coordination polymer constructed from hollow, spherical, nanometer-sized molecular faceted polyhedra and a flexible tetracarboxylate ligand designed to simultaneously assemble and cross-link these nanoballs in situ has been synthesized and structurally characterized. The crystal structure involves 2-fold interpenetration with each framework exhibiting pores of dimensions which vary from less than 1 nm to just over 2.5 nm.
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