Highly Enantioselective Insertion of Carbenoids into O−H Bonds of Phenols: An Efficient Approach to Chiral α-Aryloxycarboxylic Esters
Journal of the American Chemical Society2007Vol. 129(42), pp. 12616–12617
Citations Over TimeTop 10% of 2007 papers
Abstract
A highly efficient copper-catalyzed asymmetric carbenoid insertion into O−H bonds of phenols has been realized by using chiral spiro bisoxazoline ligands, affording α-aryloxypropionates and the related propionic acids in high yields with excellent enantiomeric excesses.
Related Papers
- → Enantiomeric enrichment of non-racemic mixtures of binaphthol with non-chiral packings(1996)47 cited
- → Catalytic Enantioselective Synthesis of Halocyclopropanes(2016)34 cited
- → Enantiomeric enrichment by the use of density differences between racemic compounds and optically active enantiomers(1995)16 cited
- → Highly enantioselective asymmetric autocatalysis of 2‐alkenyl‐ and 2‐vinyl‐5‐pyrimidyl alkanols with significant amplification of enantiomeric excess(2002)31 cited
- → Colour indicator for enantiomeric excess and assignment of the configuration of the major enantiomer of an amino acid ester(2002)26 cited