Asymmetric Synthesis of 3,4-Dihydrocoumarins by Rhodium-Catalyzed Reaction of 3-(2-Hydroxyphenyl)cyclobutanones
Journal of the American Chemical Society2007Vol. 129(40), pp. 12086–12087
Citations Over TimeTop 10% of 2007 papers
Abstract
3,4-Dihydrocoumarin derivatives were synthesized in a highly enantioselective manner from 3-(2-hydroxyphenyl)cyclobutanones through enantioselective carbon−carbon bond cleavage. A cascade reaction with electron-deficient alkenes introduced a carbon−carbon bond at the 5-position of the dihydrocoumarins.
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