Polyoxometalate Embedding of a Tetraruthenium(IV)-oxo-core by Template-Directed Metalation of [γ-SiW10O36]8−: A Totally Inorganic Oxygen-Evolving Catalyst
Journal of the American Chemical Society2008Vol. 130(15), pp. 5006–5007
Citations Over TimeTop 1% of 2008 papers
Andrea Sartorel, Mauro Carraro, Gianfranco Scorrano, Rita De Zorzi, Silvano Geremia, Neal D. McDaniel, Stefan Bernhard, Marcella Bonchio
Abstract
Solid state and solution evidence confirms the embedding of an adamantane-like, Ru4O6 fragment by the divacant, gamma-decatungstosilicate ligand. The resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h-1.
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