Oxygen and Base-Free Oxidative Heck Reactions of Arylboronic Acids with Olefins
Journal of the American Chemical Society2008Vol. 130(8), pp. 2424–2425
Citations Over TimeTop 10% of 2008 papers
Abstract
A mild and efficient protocol for palladium-catalyzed oxidative Heck reactions of arylboronic acids with both electron-rich and -deficient olefins is described. In contrast to the normal oxidative Heck coupling, this new method works in the absence of a base, oxygen, or other external oxidants. With a wide variety of substrates tolerated, the method broadens the scope of palladium-catalyzed coupling reactions.
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