Potassium(I) Amidotrihydroborate: Structure and Hydrogen Release
Journal of the American Chemical Society2010Vol. 132(34), pp. 11836–11837
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H.V.K. Diyabalanage, Tessui Nakagawa, Roshan P. Shrestha, Troy A. Semelsberger, Benjamin L. Davis, Brian L. Scott, Anthony K. Burrell, William I. F. David, Kate R. Ryan, Martin O. Jones, Peter P. Edwards
Abstract
Potassium(I) amidotrihydroborate (KNH(2)BH(3)) is a newly developed potential hydrogen storage material representing a completely different structural motif within the alkali metal amidotrihydroborate group. Evolution of 6.5 wt % hydrogen starting at temperatures as low as 80 degrees C is observed and shows a significant change in the hydrogen release profile, as compared to the corresponding lithium and sodium compounds. Here we describe the synthesis, structure, and hydrogen release characteristics of KNH(2)BH(3).
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