High Proton Conductivity in Prussian Blue Analogues and the Interference Effect by Magnetic Ordering
Journal of the American Chemical Society2010Vol. 132(19), pp. 6620–6621
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Shin‐ichi Ohkoshi, Kosuke Nakagawa, Keisuke Tomono, Kenta Imoto, Yoshihide Tsunobuchi, Hiroko Tokoro
Abstract
We observed high proton conductivities of 1.2 x 10(-3) and 1.6 x 10(-3) S cm(-1) on Co[Cr(CN)(6)](2/3).zH(2)O and V[Cr(CN)(6)](2/3).zH(2)O, respectively, and an interference effect between magnetic ordering and ionic conduction below the magnetic phase transition temperature.
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