Tuning MOF CO2 Adsorption Properties via Cation Exchange
Journal of the American Chemical Society2010Vol. 132(16), pp. 5578–5579
Citations Over TimeTop 1% of 2010 papers
Abstract
The pore volume and BET surface area of bio-MOF-1 (a), Zn(8)(ad)(4)(BPDC)(6)O.2Me(2)NH(2), is systematically modified via postsynthetic cation exchange with either tetramethylammonium, tetraethylammonium, or tetrabutylammonium cations to yield Zn(8)(ad)(4)(BPDC)(6)O.2Me(4)N (b), Zn(8)(ad)(4)(BPDC)(6)O.2Et(4)N (c), and Zn(8)(ad)(4)(BPDC)(6)O.2Bu(4)N (d), respectively. The impact that pore volume and BET surface area have on CO(2) capacity is evaluated, and it is found that materials with intermediate porosity (b and c) have the largest CO(2) capacities under the conditions studied.
Related Papers
- → Structures and Energetics of Complexes of the p-Sulfonatocalix[4]arene with Ammonium, Alkylammonium, and Tetraalkylammonium Cations in Water Using Molecular Dynamics Simulations(2004)42 cited
- → Tetraethylammonium Tetramethylammonium Tetrachlorozincate(II), [(C2H5)4N][(CH3)4N]ZnCl4(1995)11 cited
- → Tetraethylammonium Block of the BNC1 Channel(1999)16 cited
- → Inhibition of potassium-induced release of histamine from mast cells by tetraethylammonium and tetramethylammonium(1990)8 cited
- The pharmacologic activities of some hydrazonium analogues related to acetylcholine, tetramethylammonium and tetraethylammonium.(1951)