Polyoxometalatocyclophanes: Controlled Assembly of Polyoxometalate-Based Chiral Metallamacrocycles from Achiral Building Blocks
Journal of the American Chemical Society2010Vol. 132(17), pp. 5956–5957
Citations Over TimeTop 10% of 2010 papers
Abstract
The first polyoxometalatocyclophanes have been synthesized by the covalent linkage of a hexamolybdate cluster and bisarylimido ligands containing flexible chains. These metallamacrocycles are chiral, and some of them can undergo spontaneous resolution. The work provides a new protocol for preparing chiral polyoxometalates (POMs) and chiral metallamacrocycles from achiral building blocks by fastening both ends of a flexible chain onto an achiral POM to remove the symmetric center and mirror.
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