Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B−H Activation
Journal of the American Chemical Society2010Vol. 132(29), pp. 9954–9955
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Sung‐Kwan Kim, Won‐Sik Han, Tae‐Jin Kim, Tae-Young Kim, Suk Woo Nam, Mariusz P. Mitoraj, Łukasz Piękoś, Artur Michalak, Son‐Jong Hwang, Sang Ook Kang
Abstract
Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H(2) in less than 60 s at 25 degrees C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.
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