Bimetallic Reductive Elimination from Dinuclear Pd(III) Complexes
Journal of the American Chemical Society2010Vol. 132(40), pp. 14092–14103
Citations Over TimeTop 1% of 2010 papers
Abstract
In 2009, we reported C-halogen reductive elimination reactions from dinuclear Pd(III) complexes and implicated dinuclear intermediates in Pd(OAc)(2)-catalyzed C-H oxidation chemistry. Herein, we report results of a thorough experimental and theoretical investigation of the mechanism of reductive elimination from such dinuclear Pd(III) complexes, which establish the role of each metal during reductive elimination. Our results implicate reductive elimination from a complex in which the dinuclear core is intact and suggest that redox synergy between the two metals is responsible for the facile reductive elimination reactions observed.
Related Papers
- → Directly Observed Reductive Elimination of Aryl Halides from Monomeric Arylpalladium(II) Halide Complexes(2003)203 cited
- → Photoinitiated Oxidative Addition of CF3I to Gold(I) and Facile Aryl-CF3 Reductive Elimination(2014)149 cited
- → Theoretical study of Pd(0)-catalyzed carbohalogenation of alkenes: mechanism and origins of reactivities and selectivities in alkyl halide reductive elimination from Pd(ii) species(2012)101 cited
- → Reversible Reductive Elimination in Aluminum(II) Dihydrides(2020)40 cited
- → Reversible Reductive Elimination in Aluminum(II) Dihydrides(2020)15 cited