Carbon−Carbon Bond Activation by 1,1-Carboboration of Internal Alkynes
Journal of the American Chemical Society2010Vol. 132(39), pp. 13594–13595
Citations Over TimeTop 10% of 2010 papers
Abstract
Internal alkynes undergo 1,1-carboboration reactions upon treatment with boranes RB(C(6)F(5))(2) (R = C(6)F(5), CH(3)) to yield trisubstituted alkenylboranes. These products can be used as substrates in Pd-catalyzed cross-coupling reactions.
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