Pore Space Partition and Charge Separation in Cage-within-Cage Indium−Organic Frameworks with High CO2 Uptake
Journal of the American Chemical Society2010Vol. 132(48), pp. 17062–17064
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Abstract
The integration of negatively charged single-metal building blocks {In(CO2)4} and positively charged trimeric clusters {In3O} leads to three unique cage-within-cage-based porous materials, which exhibit not only high hydrothermal, thermal, and photochemical stability but also attractive structural features contributing to a very high CO2 uptake capacity of up to 119.8 L/L at 273 K and 1 atm.
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