Simple Combustion Production and Characterization of Octahydro[60]fullerene with a Non-IPR C60 Cage
Journal of the American Chemical Society2010Vol. 132(43), pp. 15093–15095
Citations Over Time
Qunhong Weng, Qiao He, Ting Liu, Huiying Huang, Jianhua Chen, Zhiyong Gao, Su‐Yuan Xie, Xin Lü, Rong‐Bin Huang, Lan‐Sun Zheng
Abstract
For the first time an easier, operable combustion method is employed for the synthesis of non-IPR fullerene, and an octahydro[60]fullerene with a non-IPR C(60) cage (C(60) isomer (#1809)C(60)) produced by combustion is isolated and characterized by MS, UV-vis, IR, and NMR spectroscopies in combination with DFT calculations. This finding shows that, in addition to chlorine, hydrogen can be an ample cataloreactant for the production of non-IPR fullerene derivatives under such conditions as arc-burning and diffusion combustion.
Related Papers
- Electronic Structure Calculations on Fullerenes and Their Derivatives(1995)
- → Size analysis of single fullerene molecules by electron microscopy(2004)144 cited
- → Hydrogenation of [76]-, [78]- and [84]-fullerenes: cage degradation(1996)15 cited
- → Probing the spatial requirements for [60]fullerene–[60]fullerene π-stacking and the syn addition of [60]fullerenes across acenes(2003)9 cited
- → Synthesis and Characterisation of Some New Ferrocenyl- and Ferrocenylalkynyl-[60]Fullerene Compounds(1997)3 cited