Steam-Stable Zeolitic Imidazolate Framework ZIF-90 Membrane with Hydrogen Selectivity through Covalent Functionalization
Journal of the American Chemical Society2010Vol. 132(44), pp. 15562–15564
Citations Over TimeTop 1% of 2010 papers
Abstract
A novel covalent functionalization strategy was developed to prepare reproducible ZIF-90 molecular sieve membranes by using 3-aminopropyltriethoxysilane as a covalent linker between the ZIF-90 layer and Al(2)O(3) support via imines condensation. The ZIF-90 membranes show high thermal and hydrothermal stabilities, and they allow the separation of hydrogen from larger gases by molecular sieving.
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