Stereospecific Cross-Coupling of Secondary Alkyl β-Trifluoroboratoamides
Journal of the American Chemical Society2010Vol. 132(48), pp. 17108–17110
Citations Over TimeTop 1% of 2010 papers
Abstract
The stereospecific cross-coupling of enantioenriched nonbenzylic secondary alkyl boron compounds has been achieved. The high selectivity toward product formation over an undesired β-H elimination pathway is achieved via an intramolecular coordination of an ancillary carbonyl to the metal center in the diorganopalladium intermediate.
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