Coordination−Insertion Copolymerization of Allyl Monomers with Ethylene
Journal of the American Chemical Society2011Vol. 133(5), pp. 1232–1235
Citations Over TimeTop 10% of 2011 papers
Abstract
Coordination-insertion copolymerization of allyl monomers with ethylene was developed by using a palladium/phosphine-sulfonate catalyst. A variety of allyl monomers, including allyl acetate, allyl alcohol, protected allylamines, and allyl halides, were copolymerized with ethylene to form highly linear copolymers that possess in-chain -CH(2)CH(CH(2)FG)- units.
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