Unprecedented Bending and Rearrangement of f-Element Sandwich Complexes Induced by Superbulky Cyclooctatetraenide Ligands
Journal of the American Chemical Society2011Vol. 133(5), pp. 1257–1259
Citations Over TimeTop 12% of 2011 papers
Volker Lorenz, B.M. Schmiege, Cristian G. Hrib, Joseph W. Ziller, Anja Edelmann, S. Blaurock, William J. Evans, Frank T. Edelmann
Abstract
The use of the superbulky cyclooctatetraenide dianion ligand [C(8)H(6)(SiPh(3))(2)](2-) (= COT(BIG)) in organo-f-element chemistry leads to unprecedented effects such as the formation of a significantly bent anionic Ce(III) sandwich complex, a novel cerocene formed by sterically induced SiPh(3) group migration, as well as the first example of a bent uranocene.
Related Papers
- A GEOMETRIC MEAN IN THE FURUTA INEQUALITY(2002)
- Susquehanna Chorale Spring Concert "Roots and Wings"(2017)
- Коммуникaтивно- прaгмaтический aнaлиз дипломaтических бумaг (нa основе вербaльных нот)(2018)
- → ФОРМИРОВAНИЕ ГОТОВНОСТИ БУДУЩИХ ПЕДAГОГОВ К ОРГAНИЗAЦИИ РAБОТЫ ПО РAЗВИТИЮ ВAЛЕОЛОГИЧЕСКОЙ КУЛЬТУРЫ ШКОЛЬНИКОВ(2023)