From Metal−Organic Squares to Porous Zeolite-like Supramolecular Assemblies
Journal of the American Chemical Society2010Vol. 132(51), pp. 18038–18041
Citations Over TimeTop 10% of 2010 papers
Abstract
We report the synthesis, structure, and characterization of two novel porous zeolite-like supramolecular assemblies, ZSA-1 and ZSA-2, having zeolite gis and rho topologies, respectively. The two compounds were assembled from functional metal-organic squares (MOSs) via directional hydrogen-bonding interactions and exhibited permanent microporosity and thermal stability up to 300 °C.
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