Exploring the Uranyl Organometallic Chemistry: From Single to Double Uranium−Carbon Bonds
Journal of the American Chemical Society2011Vol. 133(16), pp. 6162–6165
Citations Over TimeTop 10% of 2011 papers
Abstract
Uranyl organometallic complexes featuring uranium(VI)-carbon single and double bonds have been obtained from uranyl UO(2)X(2) precursors by avoiding reduction of the metal center. X-ray diffraction and density functional theory analyses of these complexes showed that the U-C and U=C bonds are polarized toward the nucleophilic carbon.
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