From Metal–Organic Framework to Nanoporous Carbon: Toward a Very High Surface Area and Hydrogen Uptake
Journal of the American Chemical Society2011Vol. 133(31), pp. 11854–11857
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Hai‐Long Jiang, Bo Liu, Ya‐Qian Lan, Kentaro Kuratani, Tomoki Akita, Hiroshi Shioyama, Zong Feng-qi, Qiang Xü
Abstract
In this work, with a zeolite-type metal-organic framework as both a precursor and a template and furfuryl alcohol as a second precursor, nanoporous carbon material has been prepared with an unexpectedly high surface area (3405 m(2)/g, BET method) and considerable hydrogen storage capacity (2.77 wt % at 77 K and 1 atm) as well as good electrochemical properties as an electrode material for electric double layer capacitors. The pore structure and surface area of the resultant carbon materials can be tuned simply by changing the calcination temperature.
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