Palladium(0)-Catalyzed Arylative Dearomatization of Phenols
Journal of the American Chemical Society2011Vol. 133(24), pp. 9282–9285
Citations Over TimeTop 10% of 2011 papers
Abstract
The palladium-catalyzed arylative dearomatization of phenols to yield spirocyclohexadienone products in good to excellent yields has been developed. Preliminary results demonstrate that the formation of the spirocyclic all-carbon quaternary center can be accomplished with high levels of enantiocontrol (up to 91% ee).
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