Supramolecular Self-Assembly of Amphiphilic Anionic Platinum(II) Complexes: A Correlation between Spectroscopic and Morphological Properties
Journal of the American Chemical Society2011Vol. 133(31), pp. 12136–12143
Citations Over TimeTop 10% of 2011 papers
Abstract
A new class of amphiphilic anionic platinum(II) bzimpy complexes has been demonstrated to show aggregation in water through Pt···Pt and π-π stacking interactions. An interesting aggregation-partial deaggregation-aggregation process and a morphological transformation from vesicles to nanofibers have been demonstrated. These changes can be systematically controlled by the variation of solvent composition and could readily be probed by UV-vis absorption, emission, NMR, transmission electron microscopy, and even with our naked eyes.
Related Papers
- → Co‐Assembly Induced Solid‐State Stacking Transformation in Amino Acid‐Based Crystals with Enhanced Physical Properties(2022)60 cited
- → CO2-Enhanced Bola-Type Supramolecular Amphiphile Constructed from Pillar[5]arene-Based Host–Guest Recognition(2018)19 cited
- → Influence of supramolecular structures in crystals on parallel stacking interactions between pyridine molecules(2013)12 cited
- → Co‐Assembly Induced Solid‐State Stacking Transformation in Amino Acid‐Based Crystals with Enhanced Physical Properties(2022)8 cited
- → Delving into the second supramolecular event approach: Aggregation of small metallo-supramolecular units supported by one or two types of non-covalent forces(2008)5 cited