Copper-Catalyzed Arylation of 1H-Perfluoroalkanes
Journal of the American Chemical Society2011Vol. 133(24), pp. 9286–9289
Citations Over TimeTop 1% of 2011 papers
Abstract
A general method has been developed for arylation of readily available 1H-perfluoroalkanes. The method employs aryl iodide and 1H-perfluoroalkane reagents, DMPU solvent, TMP(2)Zn base, and a copper chloride/phenanthroline catalyst. Preliminary mechanistic studies are reported.
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