Iron-Catalyzed Carbonylation-Peroxidation of Alkenes with Aldehydes and Hydroperoxides
Journal of the American Chemical Society2011Vol. 133(28), pp. 10756–10759
Citations Over TimeTop 10% of 2011 papers
Abstract
A three-component reaction of alkenes, aldehydes, and hydroperoxides catalyzed by FeCl(2) to β-peroxy ketones has been achieved. This three-component reaction can be also applied to the synthesis of α-carbonyl epoxides, through either a stepwise base-induced epoxidation of the separated β-peroxy ketone products or a one-pot process by simply adding base to the reaction mixture after the completion of the three-component reaction.
Related Papers
- → Parallel recognition by virtue of differentiation between ketone and aldehyde(1998)13 cited
- Progress in synthesis and modification of ketone-aldehyde resin(2006)
- Discussion on oxidation of aldehyde and ketone(2001)
- The Synthesis of 2-Furyltriisopropoxytitanium and its Reactivity to Carbonyl Compounds(1996)
- A Study on the Synthesis of 2-Thiophenyltriisopropoxytitanium and its Reactivity to Carbonyl Compounds(1994)