Pd(II)-Catalyzed para-Selective C–H Arylation of Monosubstituted Arenes
Journal of the American Chemical Society2011Vol. 133(35), pp. 13864–13867
Citations Over TimeTop 1% of 2011 papers
Abstract
Pd-catalyzed highly para-selective C-H arylation of monosubstituted arenes (including toluene) is developed for the first time using an F(+) reagent as a bystanding oxidant. This finding provides a new retrosynthetic disconnection for para-substituted biaryl synthesis via C-H/C-H cross-coupling.
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