End-Functionalized Polymerization of 2-Vinylpyridine through Initial C–H Bond Activation of N-Heteroaromatics and Internal Alkynes by Yttrium Ene–Diamido Complexes
Journal of the American Chemical Society2011Vol. 133(49), pp. 19626–19629
Citations Over TimeTop 10% of 2011 papers
Abstract
We successfully introduced end-capping functional groups to poly(2-vinylpyridine)s by initial introduction of the functional groups on yttrium catalysts through C-H bond activation of heteroaromatics and internal alkynes to the Y center via alkylyttrium-mediated σ-bond metathesis.
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