Directing the Reactivity of [HFe4N(CO)12]− toward H+ or CO2 Reduction by Understanding the Electrocatalytic Mechanism
Journal of the American Chemical Society2011Vol. 133(46), pp. 18577–18579
Citations Over TimeTop 11% of 2011 papers
Abstract
Selective reactivity of an electrocatalytically generated catalyst-hydride intermediate toward the hydrogen evolution reaction (HER) or reduction of CO(2) is key for a CO(2) reduction electrocatalyst. Under appropriate conditions, Et(4)N[Fe(4)N(CO)(12)] (Et(4)N-1) is a catalyst for the HER or for CO(2) conversion at -1.25 V vs SCE using a glassy carbon electrode.
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