Generation of a Carbene-Stabilized Bora-borylene and its Insertion into a C–H Bond
Journal of the American Chemical Society2011Vol. 133(47), pp. 19044–19047
Citations Over TimeTop 10% of 2011 papers
Philipp Bissinger, Holger Braunschweig, Alexander Damme, Rian D. Dewhurst, Thomas Kupfer, Krzysztof Radacki, Katharina Wagner
Abstract
A novel NHC adduct of a dihalodiborane(4), 1, is reduced by KC(8) with formation of the five-membered boracycle 2. The reaction most likely proceeds via C-H insertion of an intermediate NHC-stabilized free bora-borylene species.
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