Synthesis of Molybdenum Alkylidene Complexes That Contain the 2,6-Dimesitylphenylimido Ligand
Journal of the American Chemical Society2011Vol. 133(45), pp. 18142–18144
Citations Over TimeTop 12% of 2011 papers
Abstract
Compounds that have the formula M(NR)(CHR')(OR″)(Pyrrolide), where OR″ is "large" relative to NR and M = Mo or W, have been shown to be Z-selective olefin metathesis catalysts. In this communication we report a new route to Mo complexes in which the relationship between NR and OR″ has been reversed; i.e., the imido ligand is the sterically demanding 2,6-dimesitylphenylimido ligand (NAr*).
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