Rhodium(I)-Catalyzed Borylation of Nitriles through the Cleavage of Carbon–Cyano Bonds
Journal of the American Chemical Society2011Vol. 134(1), pp. 115–118
Citations Over TimeTop 10% of 2011 papers
Abstract
The reaction of aryl cyanides with diboron in the presence of a rhodium/Xantphos catalyst and DABCO affords arylboronic esters via carbon-cyano bond cleavage. This unprecedented mode of reactivity for a borylrhodium species allows the regioselective introduction of a boryl group in a late stage of synthesis.
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