Slow Magnetic Relaxation at Zero Field in the Tetrahedral Complex [Co(SPh)4]2–
Citations Over TimeTop 1% of 2011 papers
Abstract
The Ph(4)P(+) salt of the tetrahedral complex [Co(SPh)(4)](2-), possessing an S = (3)/(2) ground state with an axial zero-field splitting of D = -70 cm(-1), displays single-molecule magnet behavior in the absence of an applied magnetic field. At very low temperatures, ac magnetic susceptibility data show the magnetic relaxation time, τ, to be temperature-independent, while above 2.5 K thermally activated Arrhenius behavior is apparent with U(eff) = 21(1) cm(-1) and τ(0) = 1.0(3) × 10(-7) s. Under an applied field of 1 kOe, τ more closely approximates Arrhenius behavior over the entire temperature range. Upon dilution of the complex within a matrix of the isomorphous compound (Ph(4)P)(2)[Zn(SPh)(4)], ac susceptibility data reveal the molecular nature of the slow magnetic relaxation and indicate that the quantum tunneling pathway observed at low temperatures is likely mediated by intermolecular dipolar interactions.
Related Papers
- → 657, a method for estimating tetrahedral bond angles(2001)11 cited
- → Volume Of A Tetrahedron Revisited(2014)7 cited
- → Uniform Refinement of a Tetrahedron(1994)40 cited
- → Arrangement of Central Points on the Faces of a Tetrahedron(2021)
- → GEOMETRY OF THE TETRAHEDRON AND COMPUTATION OF THE FACE ANGLES OF A TETRAHEDRON WITH THE HELP OF CLANGUAGE(2020)