Development of Composite Inorganic Building Blocks for MOFs
Journal of the American Chemical Society2012Vol. 134(10), pp. 4517–4520
Citations Over TimeTop 1% of 2012 papers
Abstract
A general direction for diversifying metal-organic frameworks (MOFs) is demonstrated by the synthesis of composite inorganic clusters between indium and s-, d-, and f-block elements. These previously unknown heterometallic clusters, with various nuclearity, geometry, charge, and metal-to-metal ratios, significantly expand the pool of inorganic building blocks that are highly effective for the construction of porous MOFs with high gas uptake capacity.
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