Preparation of Alkyl-Modified Silicon Nanosheets by Hydrosilylation of Layered Polysilane (Si6H6)
Journal of the American Chemical Society2012Vol. 134(12), pp. 5452–5455
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Hideyuki Nakano, Mitsuru Nakano, Koji Nakanishi, Daiki Tanaka, Yusuke Sugiyama, Takashi Ikuno, Hirotaka Okamoto, Toshiaki Ohta
Abstract
Alkyl-modified crystalline silicon nanosheets 2 were synthesized and maintained the crystal structure of a Si(111) plane, in which the dangling silicon bond is stabilized by capping with the alkyl group. 2 was characterized using UV-vis, Fourier transform-infrared, and X-ray photoelectron spectroscopies; X-ray diffraction; and X-ray absorption near edge structure analysis. A model structure is proposed that has a periodicity through the nanosheet surface.
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