Graphene Oxide Based Recyclable Dehydrogenation of Ammonia Borane within a Hybrid Nanostructure
Journal of the American Chemical Society2012Vol. 134(12), pp. 5464–5467
Citations Over TimeTop 10% of 2012 papers
Abstract
The recyclable dehydrogenation of ammonia borane (AB) is achievable within a graphene oxide (GO)-based hybrid nanostructure, in which a combined modification strategy of acid activation and nanoconfinement by GO allows AB to release more than 2 equiv of pure H(2) at temperatures below 100 °C. This process yields polyborazylene (PB) as a single product and, thus, promotes the chemical regeneration of AB via reaction of PB with hydrazine in liquid ammonia.
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