Low-Temperature Synthesis of Amorphous FeP2 and Its Use as Anodes for Li Ion Batteries
Journal of the American Chemical Society2012Vol. 134(12), pp. 5532–5535
Citations Over TimeTop 10% of 2012 papers
Abstract
The reaction of Fe(N(SiMe(3))(2))(3) with PH(3) in THF at 100 °C gives amorphous FeP(2) in high yield. As an anode material in a Li ion battery, this material shows remarkable performance toward electrochemical lithiation/delithation, with gravimetric discharge and charge capacities of 1258 and 766 mA h g(-1), respectively, translating to 61% reversibility on the first cycle and a discharge capacity of 906 mA h g(-1) after 10 cycles. This translates to 66% retention of the theoretical full conversion capacity of FeP(2) (1365 mA h g(-1)).
Related Papers
- STUDY ON THE GRAVIMETRIC MEASUREMENT OF THE SWELLING BEHAVIORS OF POLYMER FILMS(2013)
- → Pillared Covalent Organic Frameworks with Balanced Volumetric and Gravimetric Hydrogen Uptake(2011)20 cited
- → Combination volumetric and gravimetric sorption instrument for high accuracy measurements of methane adsorption(2017)9 cited
- → SCREENING MAN-MADE VITREOUS FIBRE EXPOSURES BY GRAVIMETRIC DUST MEASUREMENTS(1987)4 cited
- → Report on gravimetric measurements carried out at points of the basic gravimetric net-work during 1948 and 1949 on the territory of Czechoslovakia(1952)1 cited