Immobilizing Highly Catalytically Active Pt Nanoparticles inside the Pores of Metal–Organic Framework: A Double Solvents Approach
Journal of the American Chemical Society2012Vol. 134(34), pp. 13926–13929
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A. Aijaz, Abhi Karkamkar, Young Joon Choi, Nobuko Tsumori, Ewa Rönnebro, Tom Autrey, Hiroshi Shioyama, Qiang Xü
Abstract
Ultrafine Pt nanoparticles were successfully immobilized inside the pores of a metal-organic framework, MIL-101, without aggregation of Pt nanoparticles on the external surfaces of framework by using a "double solvents" method. TEM and electron tomographic measurements clearly demonstrated the uniform three-dimensional distribution of the ultrafine Pt NPs throughout the interior cavities of MIL-101. The resulting Pt@MIL-101 composites represent the first highly active MOF-immobilized metal nanocatalysts for catalytic reactions in all three phases: liquid-phase ammonia borane hydrolysis, solid-phase ammonia borane thermal dehydrogenation, and gas-phase CO oxidation.
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