Palladium-Catalyzed C–H Activation Taken to the Limit. Flattening an Aromatic Bowl by Total Arylation

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Abstract

All 10 C-H positions on the rim of corannulene can be arylated by repetitive palladium-catalyzed C-H activation. To relieve congestion among the 10 tightly packed aryl substituents in the product, the central corannulene adopts a nearly planar geometry.

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