Design of Pt–Pd Binary Superlattices Exploiting Shape Effects and Synergistic Effects for Oxygen Reduction Reactions

Citations Over TimeTop 10% of 2012 papers

Abstract

Large-area icosahedral-AB(13)-type Pt-Pd binary superlattices (BNSLs) are fabricated through self-assembly of 6 nm Pd nanocrystals (NCs) and 13 nm Pt octahedra at a liquid-air interface. The Pt-Pd BNSLs enable a high activity toward electrocatalysis of oxygen reduction reaction (ORR) by successfully exploiting the shape effects of Pt NCs and synergistic effects of Pt-Pd into a single crystalline nanostructure. The Pt-Pd BNSLs are promising catalysts for the oxygen electrode of fuel cells.

Related Papers

• → Surface and interface engineering of hollow carbon sphere-based electrocatalysts for the oxygen reduction reaction(2021)35 cited
• → Impacts of interfacial charge transfer on nanoparticle electrocatalytic activity towards oxygen reduction(2017)54 cited
• → Coordination effect assisted synthesis of ultrathin Pt layers on second metal nanocrystals as efficient oxygen reduction electrocatalysts(2016)31 cited
• → A facile fabrication method for ultrathin NiO/Ni nanosheets as a high-performance electrocatalyst for the oxygen evolution reaction(2017)11 cited
• → P and O Co‐Doped Pt−Co Octahedral Nanocrystals as Highly Active and Stable Electrocatalysts for Oxygen Reduction Reaction(2024)4 cited