Homopolar Dihydrogen Bonding in Alkali Metal Amidoboranes: Crystal Engineering of Low-Dimensional Molecular Materials
Journal of the American Chemical Society2013Vol. 135(7), pp. 2439–2442
Citations Over TimeTop 10% of 2013 papers
Abstract
Hydrogen bonding is a predominant interaction in supramolecular chemistry. The absence of a conventional hydrogen bond donor in LiNMe(2)BH(3) and KNMe(2)BH(3) results in the formation of elaborate M···H-B polymeric arrays supported by heteropolar and homopolar H···H bonding, in a unique synergistic combination of unconventional intermolecular interactions.
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