Cooperative Supramolecular Polymerization Driven by Metallophilic Pd···Pd Interactions
Journal of the American Chemical Society2013Vol. 135(6), pp. 2148–2151
Citations Over TimeTop 1% of 2013 papers
María Múñoz, Christina Rest, Vladimir Stepanenko, Jennifer Schellheimer, Rodrigo Q. Albuquerque, Gustavo Fernández
Abstract
A new oligophenyleneethynylene (OPE)-based Pd(II) pyridyl complex has been synthesized, and its self-assembly has been investigated in solution, in the bulk state, and on surfaces. Detailed analysis of concentration- and temperature-dependent UV-vis studies in methylcyclohexane supported by DFT calculations demonstrate for the first time that cooperative supramolecular polymerization processes can be driven by metallophilic interactions.
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