Catalytic Hydrotrifluoromethylation of Unactivated Alkenes
Journal of the American Chemical Society2013Vol. 135(7), pp. 2505–2508
Citations Over TimeTop 1% of 2013 papers
Satoshi Mizuta, Stefan Verhoog, Keary M. Engle, Tanatorn Khotavivattana, Miriam L. O’Duill, Katherine M. P. Wheelhouse, Gerasimos Rassias, Maurice Médebielle, Véronique Gouverneur
Abstract
A visible-light-mediated hydrotrifluoromethylation of unactivated alkenes that uses the Umemoto reagent as the CF(3) source and MeOH as the reductant is disclosed. This effective transformation operates at room temperature in the presence of 5 mol % Ru(bpy)(3)Cl(2); the process is characterized by its operational simplicity and functional group tolerance.
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